Citation

Vajo JJ, Mertens F, Ahn CC, Bowman Jr. RC, Fultz B. J. Phys. Chem. B 2004; 108(37): 13977-13983.

Copyright

(Copyright © 2004, American Chemical Society)

DOI

10.1021/jp040060h

PMID

unavailable

Abstract

Alloying with Si is shown to destabilize the strongly bound hydrides LiH and MgH 2. For the LiH/Si system, a Li 2.35Si alloy forms upon dehydrogenation, causing the equilibrium hydrogen pressure at 490°C to increase from approximately 5 × 10 -5 to 1 bar. For the MgH 2/Si system, Mg 2Si forms upon dehydrogenation, causing the equilibrium pressure at 300°C to increase from 1.8 to >7.5 bar. Thermodynamic calculations indicate equilibrium pressures of 1 bar at approximately 20°C and 100 bar at approximately 150°C. These conditions indicate that the MgH 2/Si system, which has a hydrogen capacity of 5.0 wt %, could be practical for hydrogen storage at reduced temperatures. The LiH/Si system is reversible and can be cycled without degradation. Absorption/desorption isotherms, obtained at 400-500°C, exhibited two distinct flat plateaus with little hysteresis. The plateaus correspond to formation and decomposition of various Li suicides. The MgH 2/Si system was not readily reversible. Hydrogenation of Mg 2Si appears to be kinetically limited because of the relatively low temperature, <150°C, required for hydrogenation at 100 bar. These two alloy systems show how hydride destabilization through alloy formation upon dehydrogenation can be used to design and control equilibrium pressures of strongly bound hydrides.

Language: en

Keywords

Silicon; Heating; Degradation; Stoichiometry; Thermodynamics; X ray analysis; Desorption; Absorption; Capacitance manometers; Capacitance measurement; Cyrogenic temperatures; Data reduction; Dehydrogenation; Destabilization; Diffraction; Gravimetric densities; Hydrides; Lithium compounds; Thermocouples