Citation

Shinde SB, Tikariha L, Kumar L. ACS Omega 2023; 8(29): 25972-25987.

Copyright

(Copyright © 2023, American Chemical Society)

DOI

10.1021/acsomega.3c01963

PMID

37521631

PMCID

PMC10373471

Abstract

Flow assurance challenges associated with waxy crude oil precipitation at low ambient conditions are significant concerns for oil industries during production, transportation, and storage. Numerous methods have been employed to mitigate wax deposition and gelation issues. Since wax precipitation is temperature-sensitive, heating has emerged as a promising method to enhance oil flowability. The present work intends to examine the degelation behavior of waxy oil using rheometry, differential scanning calorimetry, and microscopy techniques. In addition, a non-isothermal flow restart simulation is performed using an in-house numerical simulator consisting of a rheological model of sol-gel transition developed in the current work. A numerical simulation of a preheated gelled pipeline demonstrates the significance of the degelation temperature.

The effects of the wax concentration, initial gel temperature, and aging period on the degelation temperature are examined. The observed degelation temperature is higher than the gelation temperature, leading to thermal hysteresis. The extent of thermal hysteresis reduces with a decrease in the heating rate. The numerical simulation uses the finite volume method with variables placed on a staggered grid. The gel heated above and below the degelation temperature shows a significant variation in axial velocity profiles. However, further heating does not affect the velocity profiles. A shear banding type of effect is observed in the axial velocity profile above the degelation temperature. Heating the gelled oil to the degelation temperature instead of the wax disappearance temperature saves excessive heating energy during storage and transport operations.

Keywords: Pipeline transportation

Language: en