Citation

Lu X, Xue X, Wang C, Shi G, Xing Y, Han Y. Fire Mater. 2022; 46(4): 651-665.

Copyright

(Copyright © 2022, John Wiley and Sons)

DOI

10.1002/fam.3013

PMID

unavailable

Abstract

Mine fire caused by coal spontaneous combustion is one of the main safety problems in mining. For the purpose of developing a more effective inhibitor to suppress the coal spontaneous combustion, a compound deoxidization gel foam inhibitor was proposed by combining sodium dithionite deoxidizer with gel foam. An experimental platform was self-built to evaluate the suppression characteristic of deoxidization gel foam. Experimental results showed that the deoxidization gel foam reduced the oxygen concentration to below 14% within 180 minutes. STA-FTIR test indicated that the deoxidization gel foam raised the active temperature from 250.57°C to 275.18°C and reduced CO2 absorption peak from 0.2926 to 0.2201 at the reaction temperature 20°C. The activation energy was also increased from 85.69 to 95.59 kJ·mol−1 in thermal decomposition combustion that exhibited an excellent flame-retardant efficacy on the coal, especially at the low temperature stage. -CH3 and -CH2 were reduced by 56.86% and 47.17% processed by deoxidization gel foam. Meanwhile, the significant reduction in the content of reductive functional groups indicated that the new inhibitor had a strong suppression capacity for coal spontaneous combustion. Based on above research, it is believed that this study will lay an important foundation in the widespread application of deoxidization gel foam technology for coal spontaneous combustion prevention in underground mines.

Language: en

Keywords

coal spontaneous combustion; deoxidization; gel foam; oxygen concentration; STA-FTIR; thermal behavior