Citation

Taylor S, Walsh ME, Becher JB, Ringelberg DB, Mannes PZ, Gribble GW. Chemosphere 2016; 167: 193-203.

Affiliation

Dartmouth College, USA.

Copyright

(Copyright © 2016, Elsevier Publishing)

DOI

10.1016/j.chemosphere.2016.09.142

PMID

27721130

Abstract

The US military is developing insensitive munitions (IM) that are less sensitive to shock and high temperatures to minimize unintentional detonations. DNAN (2,4-dinitroanisole) is one of the main ingredients of these IM formulations. During live-fire training, chunks of IM formulations are scattered by partial detonations and, once on the soil, they weather and dissolve. DNAN changes color when exposed to sunlight suggesting that it photodegrades into other compounds. We investigated the photo-degradation of DNAN both as a pure solid and as part of solid IM formulations, IMX101, IMX104 and PAX21. The concentrations of degradation products found were small, <1%, relative to DNAN concentrations. We saw transient peaks in the chromatograms indicating intermediate, unstable products but we consistently found methoxy nitrophenols and methoxy nitroanilines. We also found one unknown in most of the samples and other unknowns less frequently.

Published by Elsevier Ltd.

Language: en