Citation

Wu D, Norman F, Verplaetsen F, Van den Bulck E. J. Hazard. Mater. 2015; 307: 274-280.

Affiliation

Department of Mechanical Engineering, KU Leuven, Celestijnenlaan 300A, B3001 Leuven, Belgium.

Copyright

(Copyright © 2015, Elsevier Publishing)

DOI

10.1016/j.jhazmat.2015.12.051

PMID

26799218

Abstract

BAM furnace apparatus tests were conducted to investigate the minimum ignition temperature of coal dusts (MITC) in O2/CO2 atmospheres with an O2 mole fraction from 20 to 50%. Three coal dusts: Indonesian Sebuku coal, Pittsburgh No.8 coal and South African coal were tested. Experimental results showed that the dust explosion risk increases significantly with increasing O2 mole fraction by reducing the minimum ignition temperature for the three tested coal dust clouds dramatically (even by 100°C). Compared with conventional combustion, the inhibiting effect of CO2 was found to be comparatively large in dust clouds, particularly for the coal dusts with high volatile content. The retardation effect of the moisture content on the ignition of dust clouds was also found to be pronounced. In addition, a modified steady-state mathematical model based on heterogeneous reaction was proposed to interpret the observed experimental phenomena and to estimate the ignition mechanism of coal dust clouds under minimum ignition temperature conditions. The analysis revealed that heterogeneous ignition dominates the ignition mechanism for sub-/bituminous coal dusts under minimum ignition temperature conditions, but the decrease of coal maturity facilitates homogeneous ignition. These results improve our understanding of the ignition behaviour and the explosion risk of coal dust clouds in oxy-fuel combustion atmospheres.

Language: en