CONTACT US: Contact info
|
Citation |
Papadaki M, Stoikou V, Mantzavinos D, Rodriguez Miranda JL. Process. Saf. Environ. Prot. 2002; 80(4): 186-196. |
|
Copyright |
(Copyright © 2002, Institution of Chemical Engineers and European Federation of Chemical Engineering, Publisher Hemisphere Publishing) |
|
DOI |
|
PMID |
unavailable |
|
Abstract |
Isothermal reaction calorimetry can be used for the development of theoretically sound kinetic models, even in the case of complex reactions. In this article, the reliability of a previously developed model is further tested. The N-oxidation of 2-methylpyridine modelled by Sempere et al. (Chem Engng Process 37: 33-46) in a 2 L Mettler-Toledo heat-flow calorimeter, in IQS, Spain, is being studied at Leeds University in a 1 L SIMULAR heat-flow calorimeter. The experimental results are compared with the model developed by Sempere et al. In principle, they corroborated the previous findings. Encountered deviations have been justified; further investigation is suggested. |