Citation

Cui Y, Zhang J, Zhang T, Yang L, Zhang J, Hu X. J. Hazard. Mater. 2008; 160(1): 45-50.

Affiliation

State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing, PR China.

Copyright

(Copyright © 2008, Elsevier Publishing)

DOI

10.1016/j.jhazmat.2008.02.078

PMID

18394793

Abstract

An energetic coordination compound [Cd(DAT)(6)](ClO(4))(2) has been synthesized by using 1,5-diaminotetrazole (DAT) as ligand and its structure has been characterized by applying X-ray single crystal diffraction, elemental analysis and FT-IR spectroscopy. The central cadmium(II) cation is coordinated by six N atoms from six DAT molecules to form a six-coordinated and distorted octahedral structure. Di-dimension layer structure was formed and the layers were linked together by the extensive intermolecular hydrogen bonds between DAT ligands and ClO(4)(-) anions. Thermal decomposition mechanism of the title compound was predicted based on DSC, TG-DTG and FT-IR analyses results. The kinetic parameters of the first exothermic process of the title compound were studied by applying the Kissinger's and Ozawa-Doyle's methods. Sensitivity tests reveal that the title compound has sensitive nature.

Language: en