Citation

Schroder V, Molnarne M. J. Hazard. Mater. 2005; 121(1-3): 37-44.

Affiliation

Bundesanstalt für Materialforschung und -prüfung (BAM), Abt. Chemische Sicherheitstechnik, Unter den Eichen 87, D-12205 Berlin, Germany. volkmar.schroeder@bam.de

Copyright

(Copyright © 2005, Elsevier Publishing)

DOI

10.1016/j.jhazmat.2005.01.032

PMID

15885404

Abstract

International and European dangerous substances and dangerous goods regulations refer to the standard ISO 10156 (1996). This standard includes a test method and a calculation procedure for the determination of the flammability of gases and gas mixtures in air. The substance indices for the calculation, the so called "Tci values", which characterise the fire potential, are provided as well. These ISO Tci values are derived from explosion diagrams of older literature sources which do not take into account the test method and the test apparatus. However, since the explosion limits are influenced by apparatus parameters, the Tci values and lower explosion limits, given by the ISO tables, are inconsistent with those measured according to the test method of the same standard. In consequence, applying the ISO Tci values can result in wrong classifications. In this paper internationally accepted explosion limit test methods were evaluated and Tci values were derived from explosion diagrams. Therefore, an "open vessel" method with flame propagation criterion was favoured. These values were compared with the Tci values listed in ISO 10156. In most cases, significant deviations were found. A detailed study about the influence of inert gases on flammability is the objective of Part 2.