TY - JOUR PY - 2004// TI - The relation between phase transformation and onset of thermal degradation in nanoscale CoSi 2-polycrystalline silicon structures JO - Journal of applied physics A1 - Van Dal, M.J.H. A1 - Jawarani, D. A1 - Van Berkum, J.G.M. A1 - Kaiser, M. A1 - Kittl, J.A. A1 - Vrancken, C. A1 - De Potter, M. A1 - Lauwers, A. A1 - Maex, K. SP - 7568 EP - 7573 VL - 96 IS - 12 N2 - Insight in the thermal degradation phenomena and the relation to phase transformation is presented for cobalt disilicide (CoSi 2) on narrow polysilicon lines (linewidth ranging from 30 nm to 1 μm) using electrical and morphological analysis in the temperature range 650-900°C. When polysilicon lines are scaled laterally to 30 nm, an abrupt CoSi 2 sheet resistance increase (>1000 Ω/sq) is observed, which is attributed to silicide agglomeration. At localized positions along the 30-nm Co-silicided lines, Si/silicide layer inversion is observed. At low formation temperature (650°C), no agglomeration phenomena occur, but incidentally the transition from CoSi into CoSi 2 is delayed on the 30-nm-wide polysilicon structures to such an extent that the CoSi 2 growth virtually stops. Only using nitrogen implantation through CoSi and a CoSi 2 formation temperature of 900°C, low sheet resistance values are obtained for 35-nm-wide polysilicon lines. Based on the results obtained in the present work, we propose that the abrupt increase in the CoSi 2 sheet resistance for the narrow polysilicon lines is a consequence of a decrease in the availability of nucleation sites leading to the reduction of the CoSi/CoSi 2 transformation rate, which, in turn, results in the agglomeration of Co suicide at elevated temperature. © 2004 American Institute of Physics.

Language: en

LA - en SN - 0021-8979 UR - http://dx.doi.org/10.1063/1.1815384 ID - ref1 ER -