TY - JOUR PY - 2019// TI - Chitosan-based flame retardant coatings for polyamide 66 textiles: one-pot deposition versus layer-by-layer assembly JO - International journal of biological macromolecules A1 - Kundu, Chanchal Kumar A1 - Wang, Xin A1 - Song, Lei A1 - Hu, Yuan SP - ePub EP - ePub VL - ePub IS - ePub N2 - Chitosan (CS) and phosphorylated chitosan (PCS) were deposited onto the polyamide 66 (PA66) fabric surfaces along with poly-acrylate sodium (PAS) via 'one pot' and layer by layer (LbL) assembly methods in preparing flame retardant coatings. Subsequently, to stabilize the deposited coatings, some of the fabric samples were treated under the UV-irradiation and additionally, a thermal treatment was also carried out for the remaining fabric samples. The LbL assembled fabrics showed a better homogeneity in the coating structure over the one pot deposited fabrics as appeared in scanning electron microscopy (SEM). Nonetheless, the LbL treated fabric sample (i.e., PA66-10BL-UV) with a higher weight gain% exhibited a greater improvement in limiting oxygen index (LOI) (i.e., 23%), and a reduced peak heat release rate (pHRR) (i.e., 25%). Yet more, only the LbL assembled and thermally cross-linked fabric sample could able to retain the flame retardant behavior in the vertical burning test even after 5 washing cycles.

Copyright © 2019. Published by Elsevier B.V.

Language: en

LA - en SN - 0141-8130 UR - http://dx.doi.org/10.1016/j.ijbiomac.2019.11.220 ID - ref1 ER -