TY - JOUR PY - 2016// TI - A rare case of poisoning with a volatile substance: quantitative determination of n-butane in postmortem tissue JO - Journal of forensic sciences A1 - Hiquet, Jean A1 - Christin, Emilie A1 - Tovagliaro, Florence A1 - Gaulier, Jean-Michel A1 - Dumestre-Toulet, Véronique A1 - Gromb-Monnoyeur, Sophie SP - 549 EP - 552 VL - 62 IS - 2 N2 - Poisoning with volatile substances remains exceptional. Authors report the case of a married couple who were found in a car with a butane gas bottle: the woman was dead and her husband alleged it was an unsuccessful suicide pact. A specific research of volatile substances on postmortem samples with headspace gas chromatography-mass spectrometry following a quantitative determination was performed. The n-butane concentrations detected were composed of 610 μg/L (cardiac blood), 50 μg/kg (brain), 134 μg/kg (lungs), 285 μg/kg (liver), and 4090 μg/kg (heart) and were compatible with the rare lethal concentrations evoked in the literature. The cause of death was determined to be asphyxiation through n-butane criminal poisoning. Authors recommendation therefore is to take samples immediately and place them in properly sealed containers and hence analyzing the samples as soon as possible after collecting them or storing them under -30°C (-22°F) if analyses cannot be performed immediately.

© 2016 American Academy of Forensic Sciences.

Language: en

LA - en SN - 0022-1198 UR - http://dx.doi.org/10.1111/1556-4029.13302 ID - ref1 ER -