TY - JOUR PY - 2014// TI - Single-ion polymer electrolyte membranes enable lithium-ion batteries with a broad operating temperature range JO - ChemSusChem A1 - Cai, Weiwei A1 - Zhang, Yunfeng A1 - Li, Jing A1 - Sun, Yubao A1 - Cheng, Hansong SP - 1063 EP - 1067 VL - 7 IS - 4 N2 - Conductive processes involving lithium ions are analyzed in detail from a mechanistic perspective, and demonstrate that single ion polymeric electrolyte (SIPE) membranes can be used in lithium-ion batteries with a wide operating temperature range (25-80 °C) through systematic optimization of electrodes and electrode/electrolyte interfaces, in sharp contrast to other batteries equipped with SIPE membranes that display appreciable operability only at elevated temperatures (>60 °C). The performance is comparable to that of batteries using liquid electrolyte of inorganic salt, and the batteries exhibit excellent cycle life and rate performance. This significant widening of battery operation temperatures coupled with the inherent flexibility and robustness of the SIPE membranes makes it possible to develop thin and flexible Li-ion batteries for a broad range of applications.

Language: en

LA - en SN - 1864-5631 UR - http://dx.doi.org/10.1002/cssc.201301373 ID - ref1 ER -