TY - JOUR PY - 1999// TI - Smolder of cellulosic fabrics. IV. Participation of dye and bleach residues JO - Journal of fire sciences A1 - Dyakonov, AJ A1 - Grider, DA A1 - Ihrig, AM SP - 438 EP - 458 VL - 17 IS - 6 N2 - The oxidative decomposition of a green-and-white checkered cellulosic fabric, designated as FOR-1, comprised of four different yarns, was studied using TPR/GC and DSC techniques. Containing different alkali metal ion (AM(+)) and dye concentrations, these four yarns experienced directionally selective smolder behavior during cigarette ignition tests. Measurements were performed on the integrated fabric and on each of the four yarns. A model explaining the anisotropic smolder and high-temperature behavior of this fabric was developed. The decomposition of a heavily bleached, cellulosic sailcloth was also studied. The results showed an increase in the fabric degradation/cleavage rate compared to unbleached #6 cotton duck. The DSC spectra of the sailcloth, however, did not significantly differ from that of the washed cotton duck. Similar thermochemical behavior was observed in the blue-dyed denim fabric containing 1500 ppm potassium; the low-temperature DSC behavior of this denim was also found to be similar to that of undyed, nicotine-treated cotton duck studied in Reference [4]. These results support a model comprising the mechanisms of smolder and combustion of colored cellulosic fabrics.
LA - en SN - 0734-9041 UR - http://dx.doi.org/ ID - ref1 ER -