TY - JOUR PY - 2014// TI - Progress toward the determination of correct classification rates in fire debris analysis ii: Utilizing soft independent modeling of class analogy (SIMCA) JO - Journal of forensic sciences A1 - Waddell, Erin E. A1 - Williams, Mary R. A1 - Sigman, Michael E. SP - 927 EP - 935 VL - 59 IS - 4 N2 - A multistep classification scheme was used to detect and classify ignitable liquid residues in fire debris into the classes defined by the ASTM E1618-10 standard method. The total ion spectra (TIS) of the samples were classified by soft independent modeling of class analogy (SIMCA) with cross-validation and tested on fire debris. For detection of ignitable liquid residue, the true-positive rate was 94.2% for cross-validation and 79.1% for fire debris, with false-positive rates of 5.1% and 8.9%, respectively. Evaluation of SIMCA classifications for fire debris relative to a reviewer's examination led to an increase in the true-positive rate to 95.1%; however, the false-positive rate also increased to 15.0%. The correct classification rates for assigning ignitable liquid residues into ASTM E1618-10 classes were generally in the range of 80-90%, with the exception of gasoline samples, which were incorrectly classified as aromatic solvents following evaporative weathering in fire debris.
Language: en
LA - en SN - 0022-1198 UR - http://dx.doi.org/10.1111/1556-4029.12417 ID - ref1 ER -