TY - JOUR PY - 2012// TI - A New Kind of Molotov? Gasoline-Pool Chlorinator Mixtures JO - Journal of forensic sciences A1 - Hutches, Katherine A1 - Lord, James SP - 1064 EP - 1069 VL - 57 IS - 4 N2 - This paper investigates the reaction between pool chlorinators and gasoline. In particular, the propensity for self-ignition and the resulting chemical products were studied. An organic pool chlorinator was combined with gasoline in varying proportions in an attempt to form a hypergolic mixture. None of the combinations resulted in self-ignition, but larger quantities of chlorinator produced vigorous light-colored smoke and a solid mass containing isocyanuric acid and copper chloride. Additionally, the chlorinating abilities of different commercially available pool chlorinators were explored. When Ca(ClO)(2) and sodium dichloro-s-triazinetrione-based chlorinators were used, the presence of gasoline was still visible after 10 days, despite limited chlorination. The trichloro-s-triazinetrione-based chlorinator, however, caused efficient chlorination of the C(2) - and C(3) -alkylbenzenes, making gasoline no longer identifiable.
Language: en
LA - en SN - 0022-1198 UR - http://dx.doi.org/10.1111/j.1556-4029.2012.02078.x ID - ref1 ER -