TY - JOUR PY - 1975// TI - Determination of the concentration of explosives in air by isotope dilution analysis JO - American educational research journal A1 - St John, G. A. A1 - McReynolds, J. H. A1 - Blucher, W. G. A1 - Scott, A. C. A1 - Anbar, M. SP - 53 EP - 66 VL - 6 IS - 1-2 N2 - The concentrations in air of dinitrotoluene (DNT), trinitrotoluene (TNT), nitroglycerin (NG), ethylene glycol dinitrate (EGDN), and pentaerythritol tetranitrate (PETN) were measured at 25 degrees C under equilibrium conditions, and that of cyclomethylene trinitramine (RDX) was measured at elevated temperature by means of an isotope dilution technique. Isotopically multi-labeled compounds were synthesized and used as diluents. Field ionization mass spectrometry was used to measure the abundance ratios of the unlabeled materials. The concentrations in air at 25 degrees C of DNT, TNT, NG, EDGN, PETN, and RDX are 184, 4, 31, 37,000, 7, and 0.8 ppb v/v, respectively. The data obtained may be used for the assessment of the required sensitivity of air-monitoring detection systems.

Language: en

LA - en SN - 0002-8312 UR - http://dx.doi.org/ ID - ref1 ER -