
@article{ref1,
title="Kinetics of the nonisothermal degradation of styrene-butadiene rubber",
journal="Journal of fire sciences",
year="1999",
author="Oh, Sei-Chang and Lee, Hwa-Pyung and Yi, SC and Yoo, KO",
volume="17",
number="5",
pages="362-377",
abstract="The kinetics of the thermal degradation of styrene-butadiene rubber (SBR) have been studied using a conventional nonisothermal thermogravimetric technique at several heating rates ranging from 10 degrees C/min to 50 degrees C/min. The dynamic thermogravimetric analysis curve and its derivative have been analyzed using a variety of analytical methods reported in the literature to obtain the kinetic parameters such as activation energies, reaction orders, and pre-exponential factors. When Freeman-Carroll's method is used, apparent activation energy ranging from 105.2-258.3 kJ/mol at various heating rates is given whereas the Flynn-Wall method gave values ranging from 220.9-344.3 kJ/mol. Friedman and Ozawa methods gave apparent activation energy between 55.0-237.0 kJ/mol and 75.3-305.1 kJ/mol upon fractional weight loss, respectively.<p />",
language="en",
issn="0734-9041",
doi="",
url="http://dx.doi.org/"
}